In TeXForm#
TeXForm parses this entry as a character leaf mapped to U+27F8 (LONG LEFTWARDS DOUBLE ARROW).
\to\rightarrow\longrightarrow\mapsto\xrightarrow\Rightarrow\Leftrightarrow\leftarrow\longmapsto\hookrightarrow\Longrightarrow\Longleftarrow