In TeXForm#
TeXForm parses this entry as a character leaf mapped to U+03A3 (GREEK CAPITAL LETTER SIGMA).
\bbalpha\bbbeta\bbchi\bbdelta\bbDelta\bbdotlessi\bbdotlessj\bbepsilon\bbeta\bbgamma\bbGamma\bfbbSigma
\bfbbSigmaSymbol
The Σ symbol (Greek capital letter sigma, U+03A3), written as \bfbbSigma in LaTeX math mode.